FORMATION OF THE LAMELLAR STRUCTURE OF EMULSIONS BASED ON HYDROLYZED LECITHIN AND STEARATE SUCROSE

Authors

  • Maryana Ovcharuk National University of Food Technologies image/svg+xml Author
  • Oksana Topchiі National University of Food Technologies image/svg+xml Author
  • Alla Petryna National University of Food Technologies image/svg+xml Author

DOI:

https://doi.org/10.31548/humanhealth.4.2025.40

Keywords:

lamellar food emulsion, surfactant, cosurfactant, synergistic mixture, surface tension, emulsion stability

Abstract

Emulsion technologies play a key role in the modern food industry as a means of texturizing and encapsulating assets. Lamellar emulsions can be used in the food industry as stabilizers, texturizers and carriers of bioactive substances. The main directions are functional products with controlled release of vitamins, antioxidants, omega-3 fatty acids and probiotics. Today, the problem of finding active emulsifying systems, in particular based on known surfactants, remains relevant. Model emulsions containing different combinations of emulsifiers were prepared and analyzed. Surface tension was measured in systems containing 2% hydrolyzed lecithin, 2% sucrose stearate, and their combination. Optical microscopy was employed to confirm the formation of lamellar structures. Observations were carried out immediately after cooling the emulsions to 22 ± 2 °C and after 24 hours of storage to evaluate self-assembly processes. The combination of hydrolyzed lecithin and sucrose stearate exhibited pronounced synergistic behavior, resulting in more efficient interfacial tension reduction compared to each emulsifier used separately. The optimal emulsifier ratio was determined as 1.00% hydrolyzed lecithin and 0.75% sucrose stearate. The emulsion with a 30% fat phase prepared on this basis demonstrated high viscosity, plastic texture, stability, and satisfactory organoleptic properties. Microscopic analysis confirmed the presence of lamellar structures formed during the cooling process. The results indicate a synergistic interaction between lecithin and sucrose stearate, leading to the formation of thermodynamically stable lamellar structures. Such emulsions exhibit strong adhesion to surfaces, which is advantageous for applications in food systems such as spreads and confectionery fillings. Due to their thermal stability, these emulsions can also be used in processing operations involving moderate heating, such as pasteurization or encapsulation of bioactives, without structural degradation.

References

Bufalini, C., & Campardelli, R. (2025). Versatile emulsion-based encapsulation system production processes: A review. Processes, 13(5), 1409. https://doi:10.3390/pr13051409

Cholakova, D., & Tcholakova, S. (2024). Sucrose ester surfactants: Current understanding and emerging perspectives. Current Opinion in Colloid & Interface Science, 73, 101832. https://doi:10.1016/j.cocis.2024.101832

EFSA Panel on Food Additives and Nutrient Sources Added to Food (ANS), Mortensen, A., Aguilar, F., Crebelli, R., Di Domenico, A., Frutos, M. J., Galtier, P., Gott, D., Gundert-Remy, U., Lambré, C., Leblanc, J. C., Lindtner, O., Moldeus, P., Mosesso, P., Oskarsson, A., Parent-Massin, D., Stankovic, I., Waalkens-Berendsen, I., Woutersen, R. A., Wright, M., Younes, M., Brimer, L., Altieri, A., Christodoulidou, A., Lodi, F., & Dusemund, B. (2017). Re-evaluation of lecithins (E 322) as a food additive. EFSA Journal, 15(4), e04742. https://doi:10.2903/j.efsa.2017.4742

Fameau, Anne-Laure, Veronico, Lorenzo, Le Coeur, Clémence, Mahmoudi, Najet, Gentile, Luigi (2024). Shear and cooling effects on lamellar gel network structure: Insights from Rheo-SANS. Journal of Molecular Liquids, Volume 414, Part B, 126283. https://doi:10.1016/j.molliq.2024.126283

Kothuri, V., Han, J. H., Keum, D. H., Kwon, H. C., Kim, D. H., & Han, S. G. (2025). Utilization of emulsion gels in plant-based meat analog formulations: A review. Food Hydrocolloids, 158, 110499. https://doi:10.1016/j.foodhyd.2024.110499

Leser, M. E. (2017). Lamellar structures and their applications in food systems. Advances in Colloid and Interface Science, 247, 546–556.

Moraes, C., Anjos, J. L. V., Maruno, M., Alonso, A., & Rocha-Filho, P. (2018). Development of lamellar gel phase emulsion containing baru oil (Dipteryx alata Vog.) as a prospective delivery system for cutaneous application. Asian Journal of Pharmaceutical Sciences, 13(2), 183–190. https://doi:10.1016/j.ajps.2017.09.003

Rahim, M. A., Zahran, H. A., Jaffar, H. M., Ambreen, S., Ramadan, M. F., Al-Asmari, F., Castro-Muñoz, R., & Zongo, E. (2025). Liposomal encapsulation in food systems: A review of formulation, processing, and applications. Food Science & Nutrition, 13(8), e70587. https://doi:10.1002/fsn3.70587

Reiner, Jasmin & Ly, Tran & Liu, Lingyue & Karbstein, Heike. (2022). Melt Emulsions: Influence of the Cooling Procedure on Crystallization and Recrystallization of Emulsion Droplets and their Influence on Dispersion Viscosity upon Storage. Chemie Ingenieur Technik, 94. 10. 1002. https://doi:10.1002/cite.202100143

Taslikh, M., Mollakhalili-Meybodi, N., Alizadeh, A. M., Mousavi, M. M., Nayebzadeh, K., & Mortazavian, A. M. (2022). Mayonnaise main ingredients influence on its structure as an emulsion. Journal of Food Science and Technology, 59(6), 2108–2116. https://doi:10.1007/s13197-021-05133-1

Tippetts, M. & Martini, S. (2009). Effect of cooling rate on lipid crystallization in oil-in-water emulsions. Food Research International, 42. 847-855. https://doi:10.1016/j.foodres.2009.03.009

Uchiyama, H., et al. (2016). Formation and characterization of lamellar liquid crystalline emulsions using sucrose stearate and lecithin. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 489, 50–58.

Uriho, M., Laurent, C., & Boucher, M. (2024). Encapsulation of vitamins in multi-component emulsions: Stability and release. Food Chemistry, 434, 137236. https://doi.org/10.1016/j.foodchem.2024.137236

Wu, M., He, X., Feng, D., Li, H., Han, D., Li, Q., Zhao, B., Li, N., Liu, T., & Wang, J. (2023). The Effect of High Pressure Homogenization on the Structure of Dual-Protein and Its Emulsion Functional Properties. Foods, 12(18), 3358. https://doi:10.3390/foods12183358

Xu, Y., Yan, X., Zheng, H., Li, J., Wu, X., Xu, J., Zhen, Z., & Du, C. (2024). The application of encapsulation technology in the food industry: Classifications, recent advances, and perspectives. Food Chemistry: X, 21, 101240. https://doi:10.1016/j.fochx.2024.101240

Published

2025-12-22

Issue

Section

Food technologies

How to Cite

Ovcharuk , M., Topchiі O., & Petryna, A. (2025). FORMATION OF THE LAMELLAR STRUCTURE OF EMULSIONS BASED ON HYDROLYZED LECITHIN AND STEARATE SUCROSE. Human and nation’s Health, 3(4), 40-51. https://doi.org/10.31548/humanhealth.4.2025.40

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